Information card for entry 7005688

Structure parameters

• Formula: C26 H20 B F14 P
• Calculated formula: C26 H20 B F14 P
• SMILES: [PH+](C(C)(C)C)(C(C)(C)C)c1c(F)c(F)c(c(F)c1F)[BH](c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Tuning Lewis acidity using the reactivity of "frustrated Lewis pairs": facile formation of phosphine-boranes and cationic phosphonium-boranes.
• Authors of publication: Welch, Gregory C.; Cabrera, Lourdes; Chase, Preston A.; Hollink, Emily; Masuda, Jason D.; Wei, Pingrong; Stephan, Douglas W.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 31
• Pages of publication: 3407 - 3414
• a: 9.6218 ± 0.0012 Å
• b: 17.225 ± 0.002 Å
• c: 18.468 ± 0.002 Å
• α: 67.652 ± 0.002°
• β: 76.712 ± 0.003°
• γ: 88.612 ± 0.002°
• Cell volume: 2748.3 ± 0.6 ų
• Cell temperature: 273 ± 2 K
• Ambient diffraction temperature: 273 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0793
• Residual factor for significantly intense reflections: 0.0548
• Weighted residual factors for significantly intense reflections: 0.1537
• Weighted residual factors for all reflections included in the refinement: 0.1684
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No