Information card for entry 7005834

Structure parameters

• Formula: Bi2 Co4 H96 Na14 O116 W18
• Calculated formula: Bi2 Co4 Na14 O114 W18
• SMILES: [O]1=[W]234(O[W]567(O[W]891([O]1[Bi]%10%11%12[O]7[Co]7%13%14%15[O]=[W]%16%17%18([O]%19%20[W](O[W]%21%19(O%17)(O[W]%17%19%22([O]%23%24[W](O[W]%23(O%17)(=O)(O9)=[O][Co]9%17%231[O]7([Co]%20%24[O]258)[Bi]1(O%18)([O]%13[W]257(O[W]8%13%18(O[W]%20(O2)([O]58[Co]2([O]58[W]%24%25(O[W]5(=[O]%14)(O[W]8(O[W]58([O]%142[W](O[W]%14(O5)(=O)(O%18)O%20)(=[O]9)(O8)(O%12)=O)(O%24)=O)(O%10)(=O)O%25)(=O)O7)(O%13)=O)[O]%11%15%17)([O]%231)=O)=O)=O)O%19)(O%21)(O3)(O%22)=O)=O)=O)(=O)(O%16)(O4)O6)=O)=O)=O)=O.[Na+].O.O.[Na+].O.O.[Na+].O.O.[Na+].O.O.O.O.[Na+].O.[Na+].O.O.O.[Na+].O.O.O.O.O.[Na+].O.O.O.O.[Na+].O.O.[Na+].O.O.[Na+].O.O.[Na+].O.O.O.O.O.[Na+].O.O.O.[Na+].O.O.O.O.O.O.O.O.O
• Title of publication: The novel sandwich-type heteropolyoxotungstates [M2Bi2(beta-B-MW9O34)2]14- (M = Co(II), Zn(II)): beta-type dimeric heteropolyanions with a transition metal as the central heteroatom and Bi(III) and M as linking atoms.
• Authors of publication: Liu, Ying; Liu, Bin; Xue, Ganglin; Hu, Huaiming; Fu, Feng; Wang, Jiwu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2007
• Journal issue: 33
• Pages of publication: 3634 - 3639
• a: 13.509 ± 0.003 Å
• b: 14.427 ± 0.003 Å
• c: 15.3 ± 0.003 Å
• α: 65.28 ± 0.03°
• β: 89.35 ± 0.03°
• γ: 72.08 ± 0.03°
• Cell volume: 2553.4 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1131
• Residual factor for significantly intense reflections: 0.0656
• Weighted residual factors for significantly intense reflections: 0.1659
• Weighted residual factors for all reflections included in the refinement: 0.1992
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No