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Information card for entry 7006418
Preview
Coordinates | 7006418.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | TlPt3 triphenylphosphine cluster |
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Formula | C65 H61 F6 O5 P4 Pt3 Tl |
Calculated formula | C65 H61 F6 O5 P4 Pt3 Tl |
SMILES | F[P](F)(F)(F)(F)[F-].[Pt]1234([Pt]56([Pt]1([Tl]25([O]1CCCC1)[O]1CCCC1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)(C3=O)C6=O)([P](c1ccccc1)(c1ccccc1)c1ccccc1)C4=O)[P](c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Phosphine-ligated induced formation of thallium(I) full Pt3TlPt3 sandwich versus "open-face" TlPt3 sandwich with triangular Pt3(mu2-CO)3(PR3)3 units: synthesis and structural/spectroscopic analysis of triphenylphosphine [(mu3-Tl)Pt3(mu2-CO)3(PPh3)3]+ and its (mu3-AuPPh3)Pt3 analogue. |
Authors of publication | de Silva, Namal; Fry, Charles G.; Dahl, Lawrence F. |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2006 |
Journal issue | 8 |
Pages of publication | 1051 - 1059 |
a | 13.5297 ± 0.0015 Å |
b | 14.7786 ± 0.0017 Å |
c | 16.4101 ± 0.0018 Å |
α | 89.065 ± 0.002° |
β | 74.643 ± 0.002° |
γ | 84.216 ± 0.002° |
Cell volume | 3147.8 ± 0.6 Å3 |
Cell temperature | 173 ± 2 K |
Ambient diffraction temperature | 173 ± 2 K |
Number of distinct elements | 7 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0426 |
Residual factor for significantly intense reflections | 0.0344 |
Weighted residual factors for significantly intense reflections | 0.0853 |
Weighted residual factors for all reflections included in the refinement | 0.0981 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.116 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7006418.html
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