Information card for entry 7007836

Structure parameters

• Formula: C50 H46 I4 O P2 Rh2
• Calculated formula: C50 H46 I4 O P2 Rh2
• SMILES: [Rh]1234([P](c5ccccc5)(c5ccccc5)c5ccccc5)(I)(I)[c]5([cH]4[cH]3[cH]2[cH]15)CCOCC[c]12[cH]3[Rh]451([P](c1ccccc1)(c1ccccc1)c1ccccc1)(I)(I)[cH]3[cH]4[cH]25
• Title of publication: Binuclear half-sandwich cobalt(III) and rhodium(III) ortho-carboranedichalocogenolato complexes with ether chain-bridged bis(cyclopentadienyl) ligand.
• Authors of publication: Hou, Xiu-Feng; Liu, Shu; Wang, Hui; Chen, Yin-Qiang; Jin, Guo-Xin
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2006
• Journal issue: 44
• Pages of publication: 5231 - 5239
• a: 8.08 ± 0.003 Å
• b: 17.147 ± 0.006 Å
• c: 17.467 ± 0.006 Å
• α: 90.537 ± 0.005°
• β: 94.058 ± 0.005°
• γ: 93.095 ± 0.005°
• Cell volume: 2410.2 ± 1.5 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.112
• Residual factor for significantly intense reflections: 0.0566
• Weighted residual factors for significantly intense reflections: 0.1217
• Weighted residual factors for all reflections included in the refinement: 0.1521
• Goodness-of-fit parameter for all reflections included in the refinement: 0.908
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No