Information card for entry 7007988

Structure parameters

• Chemical name: Bis(6,6'-dimethyl-2,2'-bipyridine)copper(II) perchlorate
• Formula: C24 H24 Cl2 Cu N4 O8
• Calculated formula: C24 H24 Cl2 Cu N4 O8
• SMILES: [Cu]12([n]3c(C)cccc3c3[n]1c(ccc3)C)[n]1c(C)cccc1c1[n]2c(ccc1)C.Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-]
• Title of publication: Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+ and five-coordinate [CuL2(solvent)]2+ complexes (L = 6,6'-dimethyl-2,2'-bipyridine or 2,9-dimethyl-1,10-phenanthroline): completely gated reduction reaction of [Cu(dmp)2]2+ in nitromethane.
• Authors of publication: Itoh, Sumitaka; Kishikawa, Nobuyuki; Suzuki, Takayoshi; Takagi, Hideo D.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 6
• Pages of publication: 1066 - 1078
• a: 9.939 ± 0.008 Å
• b: 14.511 ± 0.011 Å
• c: 19.074 ± 0.017 Å
• α: 74.06 ± 0.08°
• β: 86.3 ± 0.07°
• γ: 78.02 ± 0.07°
• Cell volume: 2587 ± 4 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0609
• Residual factor for significantly intense reflections: 0.0398
• Weighted residual factors for significantly intense reflections: 0.0998
• Weighted residual factors for all reflections included in the refinement: 0.1062
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No