Information card for entry 7008379

Structure parameters

• Common name: tetrakis((mu!3$-Sulfido)-(1,2-bis(diphenylarsino)ethane)- platinum)-zinc(ii) bis(tetraphenylborate)
• Chemical name: tetrakis((μ~3~-Sulfido)-(1,2-bis(diphenylarsino)ethane)-platinum)-zinc(ii) bis(tetraphenylborate)
• Formula: C152 H136 As8 B2 Pt4 S4 Zn
• Calculated formula: C152 H136 As8 B2 Pt4 S4 Zn
• SMILES: [B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.C1C[As](c2ccccc2)(c2ccccc2)[Pt]2([S]3[Zn]4([S]5[Pt]6([As](CC[As]6(c6ccccc6)c6ccccc6)(c6ccccc6)c6ccccc6)[S]4[Pt]45[As](CC[As]4(c4ccccc4)c4ccccc4)(c4ccccc4)c4ccccc4)[S]2[Pt]23[As](CC[As]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)[As]1(c1ccccc1)c1ccccc1.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Influence of the terminal ligands on the redox properties of the {Pt2(mu-S)2} core in [Pt2(Ph2X(CH2)2XPh2)2(mu-S)2] (X = P or As) complexes and on their reactivity towards metal centres, protic acids and organic electrophiles.
• Authors of publication: Novio, Fernando; Mas-Ballesté, Rubén; Gallardo, Iluminada; González-Duarte, Pilar; Lledós, Agustí; Vila, Neus
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 16
• Pages of publication: 2742 - 2753
• a: 18.1852 ± 0.0011 Å
• b: 18.1852 ± 0.0011 Å
• c: 48.087 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 15902.4 ± 1.7 ų
• Cell temperature: 120 ± 0.1 K
• Ambient diffraction temperature: 120 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 96
• Hermann-Mauguin space group symbol: P 43 21 2
• Hall space group symbol: P 4nw 2abw
• Residual factor for all reflections: 0.0613
• Residual factor for significantly intense reflections: 0.0436
• Weighted residual factors for significantly intense reflections: 0.1009
• Weighted residual factors for all reflections included in the refinement: 0.1088
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No