Information card for entry 7008464

Structure parameters

• Formula: C29 H35 B N7 Rh Te2
• Calculated formula: C29 H35 B N7 Rh Te2
• SMILES: [Te]([Rh]12([Te]c3ccccc3)([n]3n(c(cc3C)C)[BH](n3[n]1c(cc3C)C)n1[n]2c(cc1C)C)[N]#CC)c1ccccc1
• Title of publication: Preparation of chalcogenolato-bridged dinuclear Tp*Rh-Cp*Ru complexes (Tp*= hydrotris(3,5-dimethylpyrazol-1-yl)borate, Cp*=eta(5)-pentamethylcyclopentadienyl) and binding of dioxygen to their Ru sites.
• Authors of publication: Nagao, Shoken; Seino, Hidetake; Hidai, Masanobu; Mizobe, Yasushi
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 19
• Pages of publication: 3166 - 3172
• a: 8.189 ± 0.003 Å
• b: 23.512 ± 0.009 Å
• c: 17.625 ± 0.007 Å
• α: 90°
• β: 97.054 ± 0.002°
• γ: 90°
• Cell volume: 3368 ± 2 ų
• Cell temperature: 293.1 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Residual factor for significantly intense reflections: 0.05
• Weighted residual factors for all reflections included in the refinement: 0.163
• Goodness-of-fit parameter for all reflections included in the refinement: 1.019
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No