Information card for entry 7008767

Structure parameters

• Common name: cis-bis((mu2-3,3,3',3'-tetraethyl-1,1'- isophthaloylbis(thioureato))di chloroplatinum(IV))
• Chemical name: cis-bis((mu2-3,3,3',3'-tetraethyl-1,1'-isophthaloylbis(thioureato))di chloroplatinum(IV))
• Formula: C36 H48 Cl4 N8 O4 Pt2 S4
• Calculated formula: C36 H48 Cl4 N8 O4 Pt2 S4
• Title of publication: First metallamacrocyclic complexes of Pt(iv) with 3,3,3',3'-tetraalkyl-1,1'-phenylenedicarbonylbis(thioureas): synthesis by direct or electrolytic oxidative addition of I(2), Br(2) and Cl(2).
• Authors of publication: Westra, Arjan N.; Bourne, Susan A.; Koch, Klaus R.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 17
• Pages of publication: 2916 - 2924
• a: 9.26 ± 0.0019 Å
• b: 17.863 ± 0.004 Å
• c: 14.504 ± 0.003 Å
• α: 90°
• β: 107.08 ± 0.03°
• γ: 90°
• Cell volume: 2293.3 ± 0.9 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0461
• Residual factor for significantly intense reflections: 0.0315
• Weighted residual factors for significantly intense reflections: 0.0606
• Weighted residual factors for all reflections included in the refinement: 0.0654
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No