Information card for entry 7008803

Structure parameters

• Formula: C46 H98 Ce2 F6 O19 S2 Si4
• Calculated formula: C49 H76 Ce2 F6 O16 S2 Si4
• Title of publication: The coordination chemistry of the C1-symmetric bis(silyl)methyl ligand [CH(SiMe3){SiMe(OMe)2}]- revisited: Li/M- (M = Zn, Tl, Ce), Li4- or Ce2-methoxy-bridged alkyls.
• Authors of publication: Hitchcock, Peter B.; Huang, Qigu; Lappert, Michael F.; Zhou, Meisu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 18
• Pages of publication: 2988 - 2993
• a: 10.6698 ± 0.001 Å
• b: 12.9987 ± 0.0002 Å
• c: 13.1909 ± 0.0002 Å
• α: 86.761 ± 0.001°
• β: 80.802 ± 0.001°
• γ: 70.229 ± 0.001°
• Cell volume: 1699.5 ± 0.16 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0286
• Residual factor for significantly intense reflections: 0.0266
• Weighted residual factors for significantly intense reflections: 0.0698
• Weighted residual factors for all reflections included in the refinement: 0.0713
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No