Information card for entry 7008903

Structure parameters

• Formula: C27 H22 As Co Mo O9
• Calculated formula: C27 H17 As Co Mo O9
• SMILES: [Co]12([Mo]34567(C#[O])(C#[O])([C]1(=[C]23C(=O)OC)C(=O)OC)[cH]1[cH]4[cH]5[cH]6[cH]71)([As](O)(c1ccccc1)c1ccccc1)(C#[O])C#[O]
• Title of publication: Reactions of diarsines with bi- and tri-metallic carbonyl complexes containing cobalt
• Authors of publication: Choi, Nick; Conole, Gráinne; King, Jason D.; Mays, Martin J.; McPartlin, Mary; Stone, Caroline L.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 3
• Pages of publication: 395
• a: 11.938 ± 0.004 Å
• b: 14.533 ± 0.003 Å
• c: 16.455 ± 0.003 Å
• α: 90°
• β: 99.94 ± 0.02°
• γ: 90°
• Cell volume: 2812 ± 1.2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.133
• Residual factor for significantly intense reflections: 0.0545
• Weighted residual factors for significantly intense reflections: 0.101
• Weighted residual factors for all reflections included in the refinement: 0.1247
• Goodness-of-fit parameter for all reflections included in the refinement: 0.961
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No