Guanidinates as chelating anionic ligands for early, middle and late transition metals: syntheses and crystal structures of [Ti{η2-(NPh)2CNEt2}2Cl2], [Ru{η2-(NPh)2CNHPh}3] and [Pt{η2-(NPh)2CNHPh}2]
Authors of publication
Bailey, Philip J.; Grant, Keith J.; Mitchell, Lindsey A.; Pace, Stuart; Parkin, Andrew; Parsons, Simon
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
2000
Journal issue
12
Pages of publication
1887
a
22.248 ± 0.003 Å
b
20.648 ± 0.004 Å
c
11.784 ± 0.002 Å
α
90°
β
90°
γ
90°
Cell volume
5413.3 ± 1.6 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
4
Space group number
33
Hermann-Mauguin space group symbol
P n a 21
Hall space group symbol
P 2c -2n
Residual factor for all reflections
0.0824
Residual factor for significantly intense reflections
0.0544
Weighted residual factors for all reflections
0.1358
Weighted residual factors for significantly intense reflections
0.1096
Goodness-of-fit parameter for all reflections
1.043
Goodness-of-fit parameter for significantly intense reflections
