Information card for entry 7009611

Structure parameters

• Formula: C36 H40 Au Mn N O12 P Ru3
• Calculated formula: C36 H20 Au Mn N O12 P Ru3
• SMILES: [Au]1([Ru]23([Ru]([Ru]12([N]3#C[Mn]1234(C#[O])(C#[O])[cH]5[cH]1[cH]2[cH]3[cH]45)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O])[P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Carbonylcyanometalates as building blocks: heterometallic complexes containing Mn(μ-CN)M (M = Cu, Au, Ni, Pd or Pt), Mn(μ-CN)Pd(μ-dppm)2Mn and Mn(μ-CN)M(μ-dppm)2Pd(μ-NC)Mn (M = Pt or Pd) chains of atoms and crystal structure of the mixed-metal cluster [Ru3{(μ3-NC)MnCp(CO)2}(μ-AuPPh3)(CO)10] †
• Authors of publication: Braunstein, Pierre; Oswald, Benoît; Tiripicchio, Antonio; Ugozzoli, Franco
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 13
• Pages of publication: 2195
• a: 9.339 ± 0.003 Å
• b: 12.966 ± 0.005 Å
• c: 17.725 ± 0.005 Å
• α: 69.56 ± 0.002°
• β: 80.73 ± 0.002°
• γ: 81.07 ± 0.002°
• Cell volume: 1973.5 ± 1.1 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0278
• Residual factor for significantly intense reflections: 0.0277
• Weighted residual factors for significantly intense reflections: 0.0625
• Weighted residual factors for all reflections included in the refinement: 0.0626
• Goodness-of-fit parameter for all reflections included in the refinement: 0.715
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No