Information card for entry 7009724

Structure parameters

• Formula: C43 H19 Au Cl4 Ir7 O23 P Ru3
• Calculated formula: C42.45 Au Cl2.9 Ir7 O23 P Ru3
• Title of publication: Synthesis and characterization of high-nuclearity iridium‒ruthenium and ‒gold mixed-metal carbonyl clusters, [Ir7Ru3(CO)23]−, [Ir7Ru3(CO)23(AuPPh3)] and [Ir6Ru3(CO)21(AuPPh3)]−, possessing tetrahedrally capped octahedral iridium cores obtained by capping reactions with [Ru3(CO)12] and [AuCl(PPh3)]
• Authors of publication: Chihara, Teiji; Sato, Mayumi; Konomoto, Hiromi; Kamiguchi, Satoshi; Ogawa, Haruo; Wakatsuki, Yasuo
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 14
• Pages of publication: 2295
• a: 17.271 ± 0.002 Å
• b: 17.957 ± 0.004 Å
• c: 21.029 ± 0.003 Å
• α: 90°
• β: 111.52 ± 0.01°
• γ: 90°
• Cell volume: 6067.2 ± 1.8 ų
• Cell temperature: 294.2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0507
• Weighted residual factors for all reflections included in the refinement: 0.0543
• Goodness-of-fit parameter for all reflections included in the refinement: 1.699
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No