Information card for entry 7009946

Structure parameters

• Formula: C33.5 H37.5 Cl Co0.5 Mo0.5 O P1.5
• Calculated formula: C33.5 H37.5 Cl Co0.5 Mo0.5 O P1.5
• Title of publication: Synthesis of three-membered metallaphosphaheterocycles and their ring opening with Ph2PH on mixed-metal molybdenum‒cobalt centres †
• Authors of publication: Davies, John E.; Mays, Martin J.; Raithby, Paul R.; Sarveswaran, Koshala; Solan, Gregory A.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 19
• Pages of publication: 3331
• a: 15.46 ± 0.005 Å
• b: 18.534 ± 0.005 Å
• c: 11.506 ± 0.005 Å
• α: 103.78 ± 0.03°
• β: 91.12 ± 0.03°
• γ: 76.21 ± 0.03°
• Cell volume: 3107 ± 2 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1962
• Residual factor for significantly intense reflections: 0.1044
• Weighted residual factors for all reflections: 0.3402
• Weighted residual factors for significantly intense reflections: 0.2871
• Goodness-of-fit parameter for all reflections: 1.032
• Goodness-of-fit parameter for significantly intense reflections: 1.338
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No