Information card for entry 7009980

Structure parameters

• Formula: C39 H42 Cl2 O6 P Rh
• Calculated formula: C39 H41 Cl2 O6 P Rh
• Title of publication: Novel insertion of ethynylbenzene derivatives bearing an electron-withdrawing substituent at the 4-position into a P‒C bond and their transannular insertion between a metal atom and an ipso-carbon atom of the phosphine ligand †
• Authors of publication: Yamamoto, Yasuhiro; Sugawara, Kenichiro
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 17
• Pages of publication: 2896
• a: 34.835 ± 0.007 Å
• b: 9.135 ± 0.008 Å
• c: 12.305 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3916 ± 4 ų
• Cell temperature: 299.2 K
• Ambient diffraction temperature: 299.2 K
• Number of distinct elements: 6
• Space group number: 29
• Hermann-Mauguin space group symbol: P c a 21
• Hall space group symbol: P 2c -2ac
• Residual factor for significantly intense reflections: 0.0588
• Weighted residual factors for significantly intense reflections: 0.0762
• Goodness-of-fit parameter for significantly intense reflections: 1.853
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No