Information card for entry 7010272

Structure parameters

• Chemical name: Chlorodimethylsulfoxide(N-morpholino-N'-(+)-(1R)-menthyloxycarbonylthioureato) platinum(II)
• Formula: C18 H33 Cl N2 O4 Pt S2
• Calculated formula: C18 H33 Cl N2 O4 Pt S2
• SMILES: [Pt]1([S]=C(N=C(O1)O[C@H]1C[C@H](CC[C@@H]1C(C)C)C)N1CCOCC1)(Cl)[S](=O)(C)C
• Title of publication: Synthesis, characterisation and coordination chemistry of novel chiral N,N-dialkyl-N '-menthyloxycarbonylthioureas. Crystal and molecular structures of N,N-diethyl-N '-(−)-(3R)-menthyloxycarbonylthiourea and cis-(S,S)-[Pt(L)Cl(DMSO)] [where HL = N-(+)-(3R)-menthyloxycarbonyl-N'-morpholinothiourea or N-benzoyl-N',N'-diethylthiourea]
• Authors of publication: Sacht, Cheryl; Datt, Michael S.; Otto, Stefanus; Roodt, Andreas
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2000
• Journal issue: 24
• Pages of publication: 4579
• a: 9.8964 ± 0.0006 Å
• b: 13.2721 ± 0.0008 Å
• c: 18.0016 ± 0.0011 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2364.4 ± 0.2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0393
• Residual factor for significantly intense reflections: 0.0296
• Weighted residual factors for significantly intense reflections: 0.0535
• Weighted residual factors for all reflections included in the refinement: 0.0565
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No