Redox-induced κ2–κ3 isomerisation in hydrotris(pyrazolyl)boratorhodium complexes: synthesis, structure and ESR spectroscopy of stabilised rhodium(II) species
Authors of publication
Connelly, Neil G.; Emslie, David J. H.; Geiger, William E.; Hayward, Owen D.; Linehan, Emma B.; Orpen, A. Guy; Quayle, Michael J.; Rieger, Philip H.
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
2001
Journal issue
5
Pages of publication
670
a
10.63 ± 0.003 Å
b
17.59 ± 0.004 Å
c
17.957 ± 0.003 Å
α
95.33 ± 0.02°
β
102.693 ± 0.019°
γ
107.102 ± 0.016°
Cell volume
3085.7 ± 1.3 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
8
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.2341
Residual factor for significantly intense reflections
0.0919
Weighted residual factors for significantly intense reflections
0.1513
Weighted residual factors for all reflections included in the refinement
0.2058
Goodness-of-fit parameter for all reflections included in the refinement
