Information card for entry 7010424

Structure parameters

• Formula: C32 H58 N4 O8 Rb2 Si2
• Calculated formula: C32 H58 N4 O8 Rb2 Si2
• SMILES: [Rb]12345([n]67ccccc6[N]1([Si](C)(C)C)[Rb]1687([n]74c([N]51[Si](C)(C)C)cccc7)[O]1CCOCC[O]6CC[O]8CC1)[O]1CCOCC[O]2CC[O]3CC1
• Title of publication: Cation-induced structural variations in the alkali metal derivatives of 2-trimethylsilylaminopyridine: synthesis and X-ray structures of complexes for all five metals Li‒Cs with 12-crown-4 †
• Authors of publication: Liddle, Stephen T.; Clegg, William
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 4
• Pages of publication: 402
• a: 9.8861 ± 0.0015 Å
• b: 10.0654 ± 0.0015 Å
• c: 11.9755 ± 0.0017 Å
• α: 106.949 ± 0.002°
• β: 108.155 ± 0.002°
• γ: 91.402 ± 0.002°
• Cell volume: 1074.4 ± 0.3 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0658
• Residual factor for significantly intense reflections: 0.0534
• Weighted residual factors for significantly intense reflections: 0.1289
• Weighted residual factors for all reflections included in the refinement: 0.1318
• Goodness-of-fit parameter for all reflections included in the refinement: 0.947
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No