Information card for entry 7010493

Structure parameters

• Common name: [{Li(OEt2)(PhNCH2tBu)}2]
• Formula: C30 H52 Li2 N2 O2
• Calculated formula: C30 H52 Li2 N2 O2
• Title of publication: Synthesis and structures of lithium N-trimethylsilyl- and -neopentyl-anilides and their Et2O and tmen adducts; crystal structures of [(Li{μ-N(Ph)R}-trans)2(μ-tmen)]\ιnfty (R = SiMe3 1 or CH2But 2) and [Li{μ-N(Ph)CH2But}(OEt2)]2 †
• Authors of publication: Bezombes, Jean Philippe; Hitchcock, Peter B.; Lappert, Michael F.; Merle, Philippe G.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 6
• Pages of publication: 816
• a: 9.981 ± 0.0002 Å
• b: 16.1914 ± 0.0004 Å
• c: 19.2524 ± 0.0004 Å
• α: 90°
• β: 95.796 ± 0.001°
• γ: 90°
• Cell volume: 3095.4 ± 0.12 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0839
• Residual factor for significantly intense reflections: 0.0607
• Weighted residual factors for significantly intense reflections: 0.1603
• Weighted residual factors for all reflections included in the refinement: 0.1795
• Goodness-of-fit parameter for all reflections included in the refinement: 0.955
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No