Information card for entry 7010617

Structure parameters

• Common name: (PI4)(GaI4)
• Chemical name: tetraiodophosphonium-tetraiodogallate
• Formula: Ga I8 P
• Calculated formula: Ga I8 P
• SMILES: [P+](I)(I)(I)I.[Ga]([I-])(I)(I)I
• Title of publication: Characterisation of the tetrahalophosphonium cations PBrnI4 − n+ (0 ≤ n ≤ 4) by 31P MAS NMR, IR and Raman spectroscopy and the crystal structures of PI4+AlCl4−, PI4+AlBr4− and PI4+GaI4−
• Authors of publication: Christoph Aubauer; Martin Kaupp; Thomas M. Klapötke; Heinrich Nöth; Holger Piotrowski; Wolfgang Schnick; Jürgen Senker; Max Suter
• Journal of publication: J. Chem. Soc., Dalton Trans.
• Year of publication: 2001
• Journal issue: 12
• Pages of publication: 1880 - 1889
• a: 11.0101 ± 0.0007 Å
• b: 10.4007 ± 0.0007 Å
• c: 15.1835 ± 0.0009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1738.7 ± 0.19 ų
• Cell temperature: 200 ± 3 K
• Ambient diffraction temperature: 200 ± 3 K
• Number of distinct elements: 3
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0516
• Residual factor for significantly intense reflections: 0.0377
• Weighted residual factors for significantly intense reflections: 0.0758
• Weighted residual factors for all reflections included in the refinement: 0.0785
• Goodness-of-fit parameter for all reflections included in the refinement: 0.941
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No