The synthesis and structure of lithium derivatives of the sterically encumbered β-diketiminate ligand [{(2,6-Pri2H3C6)N(CH3)C}2CH]–, and a modified synthesis of the aminoimine precursor
Authors of publication
Stender, Matthias; Wright, Robert J.; Eichler, Barrett E.; Prust, Jörg; Olmstead, Marilyn M.; Roesky, Herbert W.; Power, Philip P.
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
2001
Journal issue
23
Pages of publication
3465
a
15.053 ± 0.005 Å
b
17.944 ± 0.006 Å
c
20.034 ± 0.005 Å
α
90°
β
97.4 ± 0.02°
γ
90°
Cell volume
5366 ± 3 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
3
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0902
Residual factor for significantly intense reflections
0.0628
Weighted residual factors for significantly intense reflections
0.1489
Weighted residual factors for all reflections included in the refinement
0.1659
Goodness-of-fit parameter for all reflections included in the refinement
