Information card for entry 7010863

Structure parameters

• Formula: C18 H9 O9 P Ru2
• Calculated formula: C18 H9 O9 P Ru2
• SMILES: [Ru]123([Ru]([P]1(c1ccco1)c1ccco1)(C#[O])(C#[O])(C#[O])[C]12=[CH]3C=CO1)(C#[O])(C#[O])C#[O]
• Title of publication: A new family of phosphido-bridged dinuclear ruthenium carbonyl complexes: synthesis of [Ru2(CO)6{µ-P(C(CH)3O)2}(µ-η1,η2-C(CH)3O)] and its reactivity towards terminal alkynes
• Authors of publication: Wong, Wai-Yeung; Ting, Fai-Lung; Lam, Wai-Lim
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 20
• Pages of publication: 2981
• a: 8.2392 ± 0.0004 Å
• b: 17.7814 ± 0.0009 Å
• c: 22.116 ± 0.0011 Å
• α: 103.065 ± 0.001°
• β: 91.59 ± 0.001°
• γ: 91.399 ± 0.001°
• Cell volume: 3153.4 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0308
• Residual factor for significantly intense reflections: 0.025
• Weighted residual factors for significantly intense reflections: 0.0636
• Weighted residual factors for all reflections included in the refinement: 0.0667
• Goodness-of-fit parameter for all reflections included in the refinement: 1.002
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No