Information card for entry 7010942

Structure parameters

• Common name: [PtTiCl{(SiMe3)N(C6H4)P(C6H5)2}3].3.5(C6D6)
• Formula: C84 H69 Cl D21 N3 P3 Pt Si3 Ti
• Calculated formula: C84 H90 Cl N3 P3 Pt Si3 Ti
• Title of publication: Amidophosphine ligands as constructs for early‒late heterobimetallic complexes; the formation of an anisotropic metallocage†
• Authors of publication: Mokuolu, Q. Folashade; Avent, Anthony G.; Hitchcock, Peter B.; Love, Jason B.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2001
• Journal issue: 18
• Pages of publication: 2551
• a: 19.7739 ± 0.0003 Å
• b: 26.2764 ± 0.0006 Å
• c: 31.3507 ± 0.0006 Å
• α: 90°
• β: 103.886°
• γ: 90°
• Cell volume: 15813.4 ± 0.5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 9
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0732
• Residual factor for significantly intense reflections: 0.0429
• Weighted residual factors for significantly intense reflections: 0.0769
• Weighted residual factors for all reflections included in the refinement: 0.0865
• Goodness-of-fit parameter for all reflections included in the refinement: 1.001
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No