Information card for entry 7011136

Structure parameters

• Formula: C74 H67 F6 O3.5 P5 Pt2 S2 V
• Calculated formula: C74 H66 F6 O3.5 P5 Pt2 S2 V
• SMILES: [Pt]1([S]2[Pt]([S]1[V]2(=O)(OC)OC)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1.[P](F)(F)(F)(F)(F)[F-].O
• Title of publication: Mass spectrometry-directed synthesis of 'early‒late' sulfide-bridged heterobimetallic complexes from the metalloligand [Pt2(PPh3)4(µ-S)2] and oxo compounds of vanadium(v), molybdenum(vi) and uranium(vi)
• Authors of publication: Fong, S.-W. Audi; Yap, Woon Teck; Vittal, Jagadese J.; Henderson, William; Hor, T. S. Andy
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 8
• Pages of publication: 1826
• a: 17.7574 ± 0.0004 Å
• b: 41.8464 ± 0.0009 Å
• c: 19.3758 ± 0.0004 Å
• α: 90°
• β: 92.614 ± 0.001°
• γ: 90°
• Cell volume: 14382.9 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1338
• Residual factor for significantly intense reflections: 0.0776
• Weighted residual factors for significantly intense reflections: 0.1813
• Weighted residual factors for all reflections included in the refinement: 0.2047
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No