Information card for entry 7011510

Structure parameters

• Formula: C24 H38 Ir2 S4
• Calculated formula: C24 H38 Ir2 S4
• Title of publication: Nucleophilic addition and substitution reactions on the sulfur atoms bound to two Ir atoms. Conversion of a hydrosulfido complex [(??5-C5Me5)2Ir2(??-SH)3]Cl into a series of diiridium complexes with bridging thiolato ligands
• Authors of publication: Takagi, Fusao; Seino, Hidetake; Hidai, Masanobu; Mizobe, Yasushi
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 18
• Pages of publication: 3603
• a: 8.4984 ± 0.0007 Å
• b: 17.147 ± 0.002 Å
• c: 18.213 ± 0.002 Å
• α: 90°
• β: 98.384 ± 0.009°
• γ: 90°
• Cell volume: 2625.7 ± 0.5 ų
• Cell temperature: 298.2 K
• Ambient diffraction temperature: 298.2 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0215
• Residual factor for significantly intense reflections: 0.0215
• Weighted residual factors for significantly intense reflections: 0.0222
• Weighted residual factors for all reflections included in the refinement: 0.0222
• Goodness-of-fit parameter for all reflections included in the refinement: 1.212
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No