Information card for entry 7011594

Structure parameters

• Formula: C42 H34 Mn O4 P3 Pd
• Calculated formula: C42 H34 Mn O4 P3 Pd
• SMILES: [Pd]12([Mn]([P]1(c1ccccc1)c1ccccc1)(C#[O])(C#[O])(C#[O])C#[O])[P](CC[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Cleavage of homometallic and formation of heterometallic M‒M bonds. Serendipitous syntheses of bimetallic MnPd(µ-PPh2)(CO)4(η2-P‒P) (P‒P = dppm, dppe, dppf) and polymetallic Mn2Pd2Ag(µ-Cl)(µ-PPh2)2(µ-dppm)(CO)8
• Authors of publication: Liu, Ye; Lee, Kim Hun; Vittal, Jagadese J.; Hor, Tzi Sum Andy
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 13
• Pages of publication: 2747
• a: 10.0096 ± 0.0005 Å
• b: 10.2022 ± 0.0005 Å
• c: 18.7467 ± 0.001 Å
• α: 92.351 ± 0.001°
• β: 95.62 ± 0.001°
• γ: 94.809 ± 0.001°
• Cell volume: 1896.16 ± 0.17 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0295
• Residual factor for significantly intense reflections: 0.0265
• Weighted residual factors for significantly intense reflections: 0.0706
• Weighted residual factors for all reflections included in the refinement: 0.0714
• Goodness-of-fit parameter for all reflections included in the refinement: 1.01
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No