Information card for entry 7012015

Structure parameters

• Common name: [{(Me3Si)3C}AL(H)(OC6H3iPr2)2Li(thf)]
• Formula: C38 H70 Al Li O3 Si3
• Calculated formula: C36.416 H65.072 Al Li O3 Si3
• Title of publication: A crowded lithium diaryloxo{tris(trimethylsilyl)methyl}aluminate and a bis(triarylsiloxo){tris(trimethylsilyl)methyl}alane
• Authors of publication: Avent, Anthony G.; Eaborn, Colin; Gorrell, Ian B.; Hitchcock, Peter B.; Smith, J. David
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 21
• Pages of publication: 3971
• a: 19.071 ± 0.004 Å
• b: 20.379 ± 0.008 Å
• c: 22.142 ± 0.006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8605 ± 4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.138
• Residual factor for significantly intense reflections: 0.0813
• Weighted residual factors for significantly intense reflections: 0.2071
• Weighted residual factors for all reflections included in the refinement: 0.2436
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No