Bis(tert-butyl)sulfurdiimide, S(NBut)2, and tris(tert-butyl)sulfurtriimide, S(NBut)3: structures by gas electron diffraction, X-ray crystallography and ab initio calculations
Authors of publication
Hinchley, Sarah L.; Trickey, Peter; Robertson, Heather E.; Smart, Bruce A.; Rankin, David W. H.; Leusser, Dirk; Walfort, Bernhard; Stalke, Dietmar; Bühl, Michael; Obrey, Stephen J.
Journal of publication
Journal of the Chemical Society, Dalton Transactions
Year of publication
2002
Journal issue
24
Pages of publication
4607
a
9.3228 ± 0.0003 Å
b
9.3455 ± 0.0003 Å
c
10.6675 ± 0.0003 Å
α
70.515 ± 0.001°
β
77.571 ± 0.001°
γ
60.554 ± 0.001°
Cell volume
761.52 ± 0.04 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0343
Residual factor for significantly intense reflections
0.028
Weighted residual factors for significantly intense reflections
0.073
Weighted residual factors for all reflections included in the refinement
0.075
Goodness-of-fit parameter for all reflections included in the refinement