Information card for entry 7012086

Structure parameters

• Common name: [Zn(Me)(MesNPPh2CHPPh2NPh)].1/2(toluene)
• Formula: C44.5 H44 N2 P2 Zn
• Calculated formula: C44.5 H44 N2 P2 Zn
• Title of publication: Synthesis of C2 and Cs symmetric zinc complexes supported by bis(phosphinimino)methyl ligands and their use in ring opening polymerisation catalysis
• Authors of publication: Hill, Michael S.; Hitchcock, Peter B.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 24
• Pages of publication: 4694
• a: 25.6605 ± 0.0003 Å
• b: 14.7185 ± 0.0002 Å
• c: 20.5047 ± 0.0002 Å
• α: 90°
• β: 98.474 ± 0.001°
• γ: 90°
• Cell volume: 7659.75 ± 0.16 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0894
• Residual factor for significantly intense reflections: 0.0574
• Weighted residual factors for significantly intense reflections: 0.1357
• Weighted residual factors for all reflections included in the refinement: 0.1524
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No