Information card for entry 7012089

Structure parameters

• Common name: [Zn(OCPh3)(MesNPPh2CHPPh2NMes)].toluene
• Formula: C69 H66 N2 O P2 Zn
• Calculated formula: C69 H66 N2 O P2 Zn
• Title of publication: Synthesis of C2 and Cs symmetric zinc complexes supported by bis(phosphinimino)methyl ligands and their use in ring opening polymerisation catalysis
• Authors of publication: Hill, Michael S.; Hitchcock, Peter B.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 24
• Pages of publication: 4694
• a: 12.8791 ± 0.0002 Å
• b: 26.6119 ± 0.0005 Å
• c: 16.6536 ± 0.0004 Å
• α: 90°
• β: 100.941 ± 0.001°
• γ: 90°
• Cell volume: 5604.06 ± 0.19 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0735
• Residual factor for significantly intense reflections: 0.0485
• Weighted residual factors for significantly intense reflections: 0.103
• Weighted residual factors for all reflections included in the refinement: 0.1129
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No