Information card for entry 7012091

Structure parameters

• Common name: [Zn(OSiPh3)2(MesNPPh2CH2PPh2NMes)].2(toluene)
• Formula: C93 H90 N2 O2 P2 Si2 Zn
• Calculated formula: C93 H74 N2 O2 P2 Si2 Zn
• Title of publication: Synthesis of C2 and Cs symmetric zinc complexes supported by bis(phosphinimino)methyl ligands and their use in ring opening polymerisation catalysis
• Authors of publication: Hill, Michael S.; Hitchcock, Peter B.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 2002
• Journal issue: 24
• Pages of publication: 4694
• a: 12.7106 ± 0.0003 Å
• b: 21.5304 ± 0.0004 Å
• c: 29.7106 ± 0.0008 Å
• α: 90°
• β: 101.289°
• γ: 90°
• Cell volume: 7973.4 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0923
• Residual factor for significantly intense reflections: 0.0588
• Weighted residual factors for significantly intense reflections: 0.1369
• Weighted residual factors for all reflections included in the refinement: 0.1535
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No