Information card for entry 7012332

Structure parameters

• Common name: [Co2(C36H39N6O)(OH)2(H2O)2](ClO4)3.2H2O
• Formula: C36 H49 Cl3 Co2 N6 O19
• Calculated formula: C36 H49 Cl3 Co2 N6 O19
• Title of publication: H3O2‒, O22‒ and O2˙‒ bridging ligands in cobalt(iii) complexes of an acyclic phenolate-hinged dinucleating ligandElectronic supplementary information (ESI) available: Fig. S1: Raman spectra of [Co2(bpbp)(µ-O2)(µ-CH3CO2)]2+ (top) and the superoxo-bridged complex [Co2(bpbp)(µ-O2)(µ-CH3CO2)]3+ (bottom). Fig. S2: ESI-MS spectra of the peroxo bridged [Co2(bpbp)(µ-O2)(µ-CH3CO2)]2+. Fig. S3: ESI-MS spectrum of the superoxo bridged [Co2(bpbp)(µ-O2)(µ-CH3CO2)]3+. See http://www.rsc.org/suppdata/dt/b2/b210091f/
• Authors of publication: Ghiladi, Morten; Gomez, Jonnes T.; Hazell, Alan; Kofod, Pauli; Lumtscher, Jan; McKenzie, Christine J.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 7
• Pages of publication: 1320
• a: 11.7233 ± 0.0006 Å
• b: 13.296 ± 0.0007 Å
• c: 16.0808 ± 0.0008 Å
• α: 108.857 ± 0.001°
• β: 90.455 ± 0.001°
• γ: 112.061 ± 0.001°
• Cell volume: 2174.33 ± 0.19 ų
• Cell temperature: 120 K
• Ambient diffraction temperature: 120 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.067
• Weighted residual factors for all reflections included in the refinement: 0.052
• Goodness-of-fit parameter for all reflections included in the refinement: 1.086
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No