Information card for entry 7012374

Structure parameters

• Common name: [Mn{N(SiMe3)2}{MesNPPh2CHPPh2NMes}]
• Formula: C49 H61 Mn N3 P2 Si2
• Calculated formula: C49 H61 Mn N3 P2 Si2
• Title of publication: Tuning low-coordinate metal environments: high spin d5‒d7 complexes supported by bis(phosphinimino)methyl ligation
• Authors of publication: Evans, David J.; Hill, Michael S.; Hitchcock, Peter B.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 4
• Pages of publication: 570
• a: 23.9011 ± 0.0004 Å
• b: 15.5577 ± 0.0003 Å
• c: 12.6739 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4712.74 ± 0.14 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0463
• Residual factor for significantly intense reflections: 0.0354
• Weighted residual factors for significantly intense reflections: 0.0653
• Weighted residual factors for all reflections included in the refinement: 0.0691
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No