Information card for entry 7012438

Structure parameters

• Formula: C22 H42 Cl2 O6 P6 Rh4
• Calculated formula: C22 H42 Cl2 O6 P6 Rh4
• SMILES: C(#[O])[Rh]12345C(=O)[Rh]6783(C#[O])C(=O)[Rh]3926(C(=O)[Rh]589(C7=O)([P](C[P]4(C)C)(C)C)[P](C[P]3(C)C)(C)C)[P](C[P]1(C)C)(C)C.ClCCl
• Title of publication: Crystal structure and fluxional behaviour in solution of [Rh4(CO)6(µ-Me2PCH2PMe2)3]Electronic supplementary information (ESI) available: regression of the Eyring plot of [Rh4(CO)6(µ-Me2PCH2PMe2)3] as measured by 13C‒NMR between 169 and 293 K in CD2Cl2. 31P‒NMR spectra of [Rh4(CO)6(µ-Me2PCH2PMe2)3] in CD2Cl2 at three different temperatures. See http://www.rsc.org/suppdata/dt/b2/b210986g/
• Authors of publication: Besançon, Katya; Lumini, Tito; Laurenczy, Gàbor; Detti, Serena; Schenk, Kurt; Roulet, Raymond
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 5
• Pages of publication: 968
• a: 17.34 ± 0.004 Å
• b: 17.788 ± 0.004 Å
• c: 12.037 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3712.7 ± 1.3 ų
• Cell temperature: 130 ± 1 K
• Ambient diffraction temperature: 130 ± 1 K
• Number of distinct elements: 6
• Space group number: 62
• Hermann-Mauguin space group symbol: P n m a
• Hall space group symbol: -P 2ac 2n
• Residual factor for all reflections: 0.0349
• Residual factor for significantly intense reflections: 0.0212
• Weighted residual factors for significantly intense reflections: 0.0461
• Weighted residual factors for all reflections included in the refinement: 0.0471
• Goodness-of-fit parameter for all reflections included in the refinement: 2.089
• Diffraction radiation wavelength: 0.56086 Å
• Diffraction radiation type: AgKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No