Information card for entry 7012486

Structure parameters

• Formula: C66 H60 Cl2 Cu2 N4 O10 P2 Pt
• Calculated formula: C66 H56 Cl2 Cu2 N4 O10 P2 Pt
• SMILES: C(N1c2cccc[n]2[Cu]2([OH2])[C](#[C]2c2ccccc2)[Pt]2([P](C1)(c1ccccc1)c1ccccc1)[P](CN(Cc1ccccc1)c1cccc[n]1[Cu]1([OH2])[C]2#[C]1c1ccccc1)(c1ccccc1)c1ccccc1)c1ccccc1.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• Title of publication: Heterobimetallic Pt(ii)‒M(i) (M = Cu, Ag) eight-membered macrocyclic complexes with large-bite P,N-ligand bridgesElectronic supplementary information (ESI) available: UV-vis absorption spectra and the fluorescence excitation and emission spectra of complexes 3 and 5. See http://www.rsc.org/suppdata/dt/b2/b211301p/
• Authors of publication: Li, Qing-Shan; Xu, Feng-Bo; Cui, Da-Jun; Yu, Kai; Zeng, Xian-Shun; Leng, Xue-Bing; Song, Hai-Bin; Zhang, Zheng-Zhi
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 8
• Pages of publication: 1551
• a: 10.585 ± 0.004 Å
• b: 12.007 ± 0.004 Å
• c: 13.292 ± 0.005 Å
• α: 108.946 ± 0.006°
• β: 97.064 ± 0.005°
• γ: 98.108 ± 0.006°
• Cell volume: 1555.9 ± 1 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0559
• Residual factor for significantly intense reflections: 0.0429
• Weighted residual factors for significantly intense reflections: 0.091
• Weighted residual factors for all reflections included in the refinement: 0.1068
• Goodness-of-fit parameter for all reflections included in the refinement: 1.071
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No