Information card for entry 7012766

Structure parameters

• Common name: [{AlMe2(PhNCH2tBu)}2]
• Formula: C26 H44 Al2 N2
• Calculated formula: C26 H44 Al2 N2
• SMILES: [N]1([Al](C)(C)[N]([Al]1(C)C)(c1ccccc1)CC(C)(C)C)(c1ccccc1)CC(C)(C)C
• Title of publication: A comparative study of the behaviour of N-trimethylsilyl and N-neopentyl-anilines and 1,2-diaminobenzenes towards trimethylalane; X-ray structures of nine Al‒N compounds
• Authors of publication: Bezombes, Jean-Philippe; Gehrhus, Barbara; Hitchcock, Peter B.; Lappert, Michael F.; Merle, Philippe G.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 9
• Pages of publication: 1821
• a: 23.08 ± 0.0007 Å
• b: 9.1565 ± 0.0004 Å
• c: 15.8407 ± 0.0004 Å
• α: 90°
• β: 126.852 ± 0.002°
• γ: 90°
• Cell volume: 2678.75 ± 0.17 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0671
• Residual factor for significantly intense reflections: 0.0534
• Weighted residual factors for significantly intense reflections: 0.1336
• Weighted residual factors for all reflections included in the refinement: 0.1401
• Goodness-of-fit parameter for all reflections included in the refinement: 1.105
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No