Information card for entry 7012769

Structure parameters

• Common name: [{1,2-C6H4(NSiMe3)2AlMe}2]
• Formula: C26 H50 Al2 N4 Si4
• Calculated formula: C26 H50 Al2 N4 Si4
• SMILES: [Al]12([N](c3c(cccc3)N1[Si](C)(C)C)([Si](C)(C)C)[Al]1([N]2(c2c(cccc2)N1[Si](C)(C)C)[Si](C)(C)C)C)C
• Title of publication: A comparative study of the behaviour of N-trimethylsilyl and N-neopentyl-anilines and 1,2-diaminobenzenes towards trimethylalane; X-ray structures of nine Al‒N compounds
• Authors of publication: Bezombes, Jean-Philippe; Gehrhus, Barbara; Hitchcock, Peter B.; Lappert, Michael F.; Merle, Philippe G.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 9
• Pages of publication: 1821
• a: 17.1014 ± 0.0005 Å
• b: 11.6579 ± 0.0003 Å
• c: 17.7117 ± 0.0005 Å
• α: 90°
• β: 100.098 ± 0.002°
• γ: 90°
• Cell volume: 3476.42 ± 0.17 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0759
• Residual factor for significantly intense reflections: 0.0573
• Weighted residual factors for significantly intense reflections: 0.1434
• Weighted residual factors for all reflections included in the refinement: 0.1581
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No