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Information card for entry 7012843
Preview
Coordinates | 7012843.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | trans-[Co(dtc)~2~{P(OMe)~2~Ph}~2~]BF~4~.(CH~3~)~2~CO |
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Chemical name | trans-Bis(dimethyldithiocarbamato)bis(dimethyl phenylphosphonito)cobalt(III) Tetrafluoroborate Acetone solvate |
Formula | C25 H40 B Co F4 N2 O5 P2 S4 |
Calculated formula | C25 H40 B Co F4 N2 O5 P2 S4 |
Title of publication | Syntheses, crystal structures and isomerization kinetics of a series of [Co(dtc)2{P(OMe)3�?�nPhn}2]+ (n = 0?2) complexes (dtc? = N,N-dimethyldithiocarbamate): role of ?-donicity, ?-acidity, and cone angle of the P-ligands in the trans influence and trans effectElectronic supplementary information (ESI) available: bond lengths and angles for all of the trans- and cis-complexes are summarized in Table S1?S6. The structures of the trans-isomers with different orientations and conformations of the OMe and Ph substituents on the P atoms are shown in Figs. S1?S3. See http://www.rsc.org/suppdata/dt/b3/b301712e/ |
Authors of publication | Iwatsuki, Satoshi; Kashiwamura, Shinsaku; Kashiwabara, Kazuo; Suzuki, Takayoshi; Takagi, Hideo D. |
Journal of publication | Dalton Transactions |
Year of publication | 2003 |
Journal issue | 11 |
Pages of publication | 2280 |
a | 11.025 ± 0.002 Å |
b | 12.5943 ± 0.0017 Å |
c | 25.5808 ± 0.0018 Å |
α | 90° |
β | 94.41 ± 0.01° |
γ | 90° |
Cell volume | 3541.4 ± 0.8 Å3 |
Cell temperature | 296 ± 2 K |
Ambient diffraction temperature | 296 ± 2 K |
Number of distinct elements | 9 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/a 1 |
Hall space group symbol | -P 2yab |
Residual factor for all reflections | 0.1789 |
Residual factor for significantly intense reflections | 0.0447 |
Weighted residual factors for significantly intense reflections | 0.1427 |
Weighted residual factors for all reflections included in the refinement | 0.188 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.006 |
Diffraction radiation wavelength | 0.71069 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/7012843.html
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