Information card for entry 7012907

Structure parameters

• Chemical name: Tetraphenylphosphoniumtrichlorocycloocteneplatinum(II)
• Formula: C32 H34 Cl3 P Pt
• Calculated formula: C32 H34 Cl3 P Pt
• SMILES: [Pt]1(Cl)(Cl)(Cl)[CH]2=[CH]1CCCCCC2.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Bridge-splitting kinetics, equilibria and structures of trans-biscyclooctene complexes of platinum(ii)Electronic supplementary information (ESI) available: observed pseudo-first order rate constants for bridge splitting reactions, absorbance versus added ligand concentrations for equlibrium constant determinations and complete crystallographic details in CIF format. See http://www.rsc.org/suppdata/dt/b3/b302482m/
• Authors of publication: Otto, Stefanus; Roodt, Andreas; Elding, Lars I.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 12
• Pages of publication: 2519
• a: 11.227 ± 0.002 Å
• b: 14.746 ± 0.003 Å
• c: 18.901 ± 0.004 Å
• α: 90°
• β: 107.18 ± 0.03°
• γ: 90°
• Cell volume: 2989.5 ± 1.1 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0914
• Residual factor for significantly intense reflections: 0.0354
• Weighted residual factors for significantly intense reflections: 0.0675
• Weighted residual factors for all reflections included in the refinement: 0.0777
• Goodness-of-fit parameter for all reflections included in the refinement: 0.89
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No