Information card for entry 7012949

Structure parameters

• Chemical name: [(1,3-(diphenylphosphino)propane)palladium(II)- 1-carbadodecaboranyl][1-carbadodecaboranyl]
• Formula: C29 H50 B22 O0.22 P2 Pd
• Calculated formula: C29 H50 B22 O0.22 P2 Pd
• Title of publication: Dihalogeno(diphosphane)metal(ii) complexes (metal = Co, Ni, Pd) as pre-catalysts for the vinyl/addition polymerization of norbornene ? elucidation of the activation process with B(C6F5)3/AlEt3 or Ag[closo-1-CB11H12] and evidence for the in situ formation of ?naked? Pd2+ as a highly active speciesElectronic supplementary information (ESI) available: Full 1H, 19F and 31P NMR data of compounds 5 and 6 in combination with different amounts of B(C6F5)3/AlEt3. See http://www.rsc.org/suppdata/dt/b3/b302937a/
• Authors of publication: Lassahn, Paul-Gerhard; Lozan, Vasile; Wu, Biao; Weller, Andrew S.; Janiak, Christoph
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 23
• Pages of publication: 4437
• a: 10.96 ± 0.0008 Å
• b: 11.4034 ± 0.0009 Å
• c: 18.4232 ± 0.0014 Å
• α: 102.192 ± 0.001°
• β: 98.503 ± 0.001°
• γ: 107.025 ± 0.001°
• Cell volume: 2097.1 ± 0.3 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0971
• Residual factor for significantly intense reflections: 0.0522
• Weighted residual factors for significantly intense reflections: 0.0933
• Weighted residual factors for all reflections included in the refinement: 0.109
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No