Information card for entry 7012951

Structure parameters

• Chemical name: [Bis(1,2-(diphenylphosphino)ethane)palladium(II)]- di[chloro-tris(pentafluorophenyl)borate]- tetrakis methylene chloride
• Formula: C92 H56 B2 Cl10 F30 P4 Pd
• Calculated formula: C92 H56 B2 Cl10 F30 P4 Pd
• Title of publication: Dihalogeno(diphosphane)metal(ii) complexes (metal = Co, Ni, Pd) as pre-catalysts for the vinyl/addition polymerization of norbornene ? elucidation of the activation process with B(C6F5)3/AlEt3 or Ag[closo-1-CB11H12] and evidence for the in situ formation of ?naked? Pd2+ as a highly active speciesElectronic supplementary information (ESI) available: Full 1H, 19F and 31P NMR data of compounds 5 and 6 in combination with different amounts of B(C6F5)3/AlEt3. See http://www.rsc.org/suppdata/dt/b3/b302937a/
• Authors of publication: Lassahn, Paul-Gerhard; Lozan, Vasile; Wu, Biao; Weller, Andrew S.; Janiak, Christoph
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 23
• Pages of publication: 4437
• a: 10.909 ± 0.003 Å
• b: 14.192 ± 0.003 Å
• c: 16.104 ± 0.004 Å
• α: 103.811 ± 0.004°
• β: 104.192 ± 0.004°
• γ: 91.833 ± 0.004°
• Cell volume: 2336.4 ± 1 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0769
• Residual factor for significantly intense reflections: 0.0454
• Weighted residual factors for significantly intense reflections: 0.0995
• Weighted residual factors for all reflections included in the refinement: 0.1135
• Goodness-of-fit parameter for all reflections included in the refinement: 0.979
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No