Information card for entry 7013051

Structure parameters

• Common name: [AlCl2(AMPTMSDCC)]
• Formula: C22 H37 Al Cl2 N4 Si
• Calculated formula: C22 H37 Al Cl2 N4 Si
• SMILES: Cl[Al]1(Cl)[n]2c(N=C(N([Si](C)(C)C)C3CCCCC3)N1C1CCCCC1)cccc2C
• Title of publication: Pyridyl donor induced 1,3-silyl migration in metal complexes of the guanidine CyHNC{N(SiMe3)Py}NCy, Py = 2-(6-MeC5H3N)
• Authors of publication: Cole, Marcus L.; Junk, Peter C.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 11
• Pages of publication: 2109
• a: 31.997 ± 0.006 Å
• b: 9.1761 ± 0.0018 Å
• c: 21.752 ± 0.004 Å
• α: 90°
• β: 125.82 ± 0.03°
• γ: 90°
• Cell volume: 5179 ± 3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0674
• Residual factor for significantly intense reflections: 0.0492
• Weighted residual factors for significantly intense reflections: 0.1293
• Weighted residual factors for all reflections included in the refinement: 0.1397
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No