Information card for entry 7013100

Structure parameters

• Common name: Platinum-Thallium Carbonyl Phosphine Sandwich Cluster
• Formula: C42 H90 F6 O6 P7 Pt6 Tl
• Calculated formula: C42 H90 F6 O6 P7 Pt6 Tl
• Title of publication: Formation of thallium(i) sandwich M3TlM3 clusters, [(μ6-Tl)M6(μ2-CO)6(PEt3)6]+ (M = Pt, Pd), with two unconnected triangular M3(μ2-CO)3(PEt3)3 units: implications of comparative analysis of isostructural 5d106s2 Tl(i)‒(M3)2 sandwiches (M = Pt, Pd) with known 5d10 Au(i)‒(Pt3)2 sandwich
• Authors of publication: Mednikov, Evgueni G.; Dahl, Lawrence F.
• Journal of publication: Dalton Transactions
• Year of publication: 2003
• Journal issue: 15
• Pages of publication: 3117 - 3125
• a: 22.9611 ± 0.0013 Å
• b: 24.4812 ± 0.0014 Å
• c: 22.4513 ± 0.0013 Å
• α: 90°
• β: 94.795 ± 0.001°
• γ: 90°
• Cell volume: 12576.1 ± 1.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0283
• Residual factor for significantly intense reflections: 0.0235
• Weighted residual factors for significantly intense reflections: 0.0544
• Weighted residual factors for all reflections included in the refinement: 0.0558
• Goodness-of-fit parameter for all reflections included in the refinement: 1.116
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No