Crystallography Open Database

Information card for entry 7013715

Preview

Coordinates	7013715.cif
Original paper (by DOI)	HTML

Structure parameters

Common name	(Sm(MesNPPh2CHPPh2NMes)) 2.5(toluene)
Formula	C103.5 H106 N4 P4 Sm
Calculated formula	C103.5 H94 N4 P4 Sm
Title of publication	Synthesis of a homoleptic Sm(ii) bis(phosphinimino)methanide
Authors of publication	Hill, Michael S.; Hitchcock, Peter B.
Journal of publication	Dalton Transactions
Year of publication	2003
Journal issue	24
Pages of publication	4570
a	15.167 ± 0.0001 Å
b	15.8289 ± 0.0002 Å
c	22.033 ± 0.0003 Å
α	68.814 ± 0.001°
β	75.887 ± 0.001°
γ	75.659 ± 0.001°
Cell volume	4708.17 ± 0.1 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	5
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0866
Residual factor for significantly intense reflections	0.0635
Weighted residual factors for significantly intense reflections	0.1609
Weighted residual factors for all reflections included in the refinement	0.1749
Goodness-of-fit parameter for all reflections included in the refinement	1.067
Diffraction radiation probe	x-ray
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

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