Information card for entry 7013794

Structure parameters

• Formula: C70 H70 Cl4 P2 Rh4
• Calculated formula: C70 H70 Cl4 P2 Rh4
• Title of publication: Extending the coordination capabilities of tertiary phosphines and arsines: preparation, molecular structure, and reactivity of dinuclear rhodium complexes with PR3 and AsR3 in a doubly bridging coordination mode.
• Authors of publication: Pechmann, Thomas; Brandt, Carsten D.; Werner, Helmut
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2004
• Journal issue: 6
• Pages of publication: 959 - 966
• a: 22.2854 ± 0.0011 Å
• b: 15.115 ± 0.0007 Å
• c: 19.2895 ± 0.0009 Å
• α: 90°
• β: 101.878 ± 0.001°
• γ: 90°
• Cell volume: 6358.4 ± 0.5 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0249
• Residual factor for significantly intense reflections: 0.0228
• Weighted residual factors for significantly intense reflections: 0.0541
• Weighted residual factors for all reflections included in the refinement: 0.0551
• Goodness-of-fit parameter for all reflections included in the refinement: 1.078
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No