Chalcogenidobis(ene-1,2-dithiolate)molybdenum(IV) complexes (chalcogenide E = O, S, Se): probing Mo≡E and ene-1,2-dithiolate substituent effects on geometric and electronic structure.
Authors of publication
Sugimoto, Hideki; Tano, Hiroyuki; Suyama, Koichiro; Kobayashi, Tomoya; Miyake, Hiroyuki; Itoh, Shinobu; Mtei, Regina P.; Kirk, Martin L.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2011
Journal volume
40
Journal issue
5
Pages of publication
1119 - 1131
a
12.8056 ± 0.0005 Å
b
18.2219 ± 0.0008 Å
c
31.5759 ± 0.0015 Å
α
90°
β
90°
γ
90°
Cell volume
7368 ± 0.6 Å3
Cell temperature
100.1 K
Ambient diffraction temperature
100.1 K
Number of distinct elements
6
Space group number
61
Hermann-Mauguin space group symbol
P b c a
Hall space group symbol
-P 2ac 2ab
Residual factor for significantly intense reflections
0.0712
Weighted residual factors for all reflections included in the refinement
0.1457
Goodness-of-fit parameter for all reflections included in the refinement
