Information card for entry 7015067

Structure parameters

• Chemical name: [Ru(bpy)(CH3CN)2(dppcb)PdCl2](SbF6)2
• Formula: C66 H58 Cl2 F12 N4 O2 P4 Pd Ru Sb2
• Calculated formula: C66 H58 Cl2 F12 N4 O2 P4 Pd Ru Sb2
• SMILES: [Pd]1([P]([C@@H]2[C@H]3[P]([Ru]4([P]([C@H]3[C@@H]2[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)([N]#CC)([N]#CC)[n]1ccccc1c1[n]4cccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(Cl)Cl.[Sb](F)(F)(F)([F-])(F)F.[Sb](F)(F)(F)(F)([F-])F.O.O
• Title of publication: Surprising photochemical reactivity and visible light-driven energy transfer in heterodimetallic complexes.
• Authors of publication: Eller, Sylvia; Trettenbrein, Barbara; Fessler, Markus; Haringer, Stephan; Ruggenthaler, Martin; Gutmann, Rene; van der Veer, Wytze E.; Kopacka, Holger; Müller, Thomas; Obendorf, Dagmar; Brüggeller, Peter
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 15
• Pages of publication: 3815 - 3829
• a: 14.4448 ± 0.0006 Å
• b: 21.0505 ± 0.0009 Å
• c: 26.0985 ± 0.0009 Å
• α: 90°
• β: 99.057 ± 0.002°
• γ: 90°
• Cell volume: 7836.8 ± 0.5 ų
• Cell temperature: 243 ± 2 K
• Ambient diffraction temperature: 243 ± 2 K
• Number of distinct elements: 10
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1114
• Residual factor for significantly intense reflections: 0.0625
• Weighted residual factors for significantly intense reflections: 0.1632
• Weighted residual factors for all reflections included in the refinement: 0.2479
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No