Intramolecular hydrogen bonding controls 1,3-N,S- vs. 1,5-S,S'-coordination in Ni(II) complexes of N-thiophosphorylated thioureas RNHC(S)NHP(S)(OiPr)2.
Authors of publication
Babashkina, Maria G.; Safin, Damir A.; Bolte, Michael; Srebro, Monika; Mitoraj, Mariusz; Uthe, André; Klein, Axel; Köckerling, Martin
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2011
Journal volume
40
Journal issue
13
Pages of publication
3142 - 3153
a
7.4084 ± 0.0007 Å
b
9.751 ± 0.0008 Å
c
10.2595 ± 0.0009 Å
α
80.832 ± 0.007°
β
76.351 ± 0.007°
γ
70.632 ± 0.007°
Cell volume
676.79 ± 0.11 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
173 ± 2 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0311
Residual factor for significantly intense reflections
0.0294
Weighted residual factors for significantly intense reflections
0.0764
Weighted residual factors for all reflections included in the refinement
0.0776
Goodness-of-fit parameter for all reflections included in the refinement