Information card for entry 7015293

Structure parameters

• Formula: C24 H28 N4 O8 Zn2
• Calculated formula: C24 H28 N4 O8 Zn2
• SMILES: C1(O[Zn]23([N](c4c(cccc4)[O]3[Zn]34(OC(=C(C(=O)C)N=[N]4c4c([O]23)cccc4)C)[OH]C)=NC=1C(=O)C)[OH]C)C
• Title of publication: Zinc(ii) ortho-hydroxyphenylhydrazo-β-diketonate complexes and their catalytic ability towards diastereoselective nitroaldol (Henry) reaction.
• Authors of publication: Kopylovich, Maximilian N.; Mac Leod, Tatiana C. O.; Mahmudov, Kamran T.; Guedes da Silva, M Fátima C; Pombeiro, Armando J. L.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2011
• Journal volume: 40
• Journal issue: 19
• Pages of publication: 5352 - 5361
• a: 8.0218 ± 0.0004 Å
• b: 8.8006 ± 0.0003 Å
• c: 10.328 ± 0.0005 Å
• α: 93.178 ± 0.002°
• β: 103.423 ± 0.003°
• γ: 111.763 ± 0.002°
• Cell volume: 650.53 ± 0.05 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0468
• Residual factor for significantly intense reflections: 0.0337
• Weighted residual factors for significantly intense reflections: 0.0734
• Weighted residual factors for all reflections included in the refinement: 0.0793
• Goodness-of-fit parameter for all reflections included in the refinement: 0.969
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No