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Information card for entry 7015786
Preview
Coordinates | 7015786.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C30 H78 Mo2 N3 O6 P Si4 |
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Calculated formula | C30 H78 Mo2 N3 O6 P Si4 |
SMILES | [Mo]([Mo]1([N]([Si](C)(C)C)=P(N([Si](C)(C)C)[Si](C)(C)C)(N1[Si](C)(C)C)OC(C)C)(OC(C)C)OC(C)C)(OC(C)C)(OC(C)C)OC(C)C |
Title of publication | Reactions of ((i)PrO)3M≡M(O(i)Pr)3 (M = Mo, W) with low-coordinate phosphorus compounds. Formation of the first four-membered planar metallacycles, containing an M≡M triple bond. |
Authors of publication | Kovalenko, Oleksandr O.; Brusylovets, Oleksii A.; Kinzhybalo, Vasyl; Lis, Tadeusz; Brusilovets, Anatolii I. |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2011 |
Journal volume | 40 |
Journal issue | 18 |
Pages of publication | 4814 - 4817 |
a | 11.76 ± 0.003 Å |
b | 13.424 ± 0.004 Å |
c | 16.339 ± 0.005 Å |
α | 88.52 ± 0.03° |
β | 86.5 ± 0.03° |
γ | 64.5 ± 0.03° |
Cell volume | 2323.8 ± 1.3 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 7 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0559 |
Residual factor for significantly intense reflections | 0.0448 |
Weighted residual factors for significantly intense reflections | 0.1128 |
Weighted residual factors for all reflections included in the refinement | 0.1191 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.133 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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